POC-OC-122408-RTP Crystal

  • High damage threshold, approximately 1.8 times higher than KTP, ensuring reliability in high-power laser systems.
  • Excellent electro-optical properties, with fast response times for signal modulation up to 60 kHz.
  • Non-hygroscopic and chemically stable, offering long-term durability in varied environments.
  • Wide transmission range from 350 nm to 4500 nm, making it versatile for nonlinear and electro-optical applications.
  • High resistivity and piezoelectric-free operation, ensuring stable performance in demanding applications.

Customizable Components Available for This Material to Meet Your Specific Needs!

Material General Description of RTP Crystal

Rubidium Titanyl Phosphate (RTP, RbTiOPO₄) is an advanced nonlinear and electro-optical crystal widely used for high-performance laser systems and electro-optic applications. As an isomorphic crystal of KTP, RTP inherits many of the desirable properties of its counterpart while providing enhanced features such as a higher damage threshold, high resistivity, and no piezoelectric ringing. These characteristics make RTP ideal for high-repetition-rate and high-energy laser systems.

RTP crystals are non-hygroscopic and chemically stable, eliminating the need for specialized storage and maintenance conditions. With a wide transmission range from 350 nm to 4500 nm and excellent optical clarity, RTP is suitable for a broad range of applications, including frequency doubling, optical parametric oscillation, and electro-optic modulation. Its superior thermal and mechanical properties further enhance its reliability and performance, making RTP a preferred choice for scientific, industrial, and medical applications

General Applications and Examples

RTP crystals are versatile and widely used in various applications due to their exceptional nonlinear and electro-optical properties. Below are some examples:

  1. Frequency Doubling and Mixing:
  • RTP crystals are utilized in frequency doubling of Nd:YAG and Nd:YVO₄ lasers to generate visible and UV laser outputs.
  • Example: Conversion of 1064 nm laser wavelength to 532 nm (green) or UV wavelengths in laser systems for precision machining and scientific research.
  1. Electro-Optic Modulation:
  • RTP’s high electro-optic coefficients make it ideal for modulating laser signals with high efficiency and fast response times.
  • Example: Electro-optic modulators in fiber optic communication systems, offering high-speed signal control without piezoelectric ringing.
  1. Optical Parametric Oscillation (OPO):
  • RTP is used in OPO systems to produce tunable laser outputs in the visible and infrared ranges.
  • Example: Generation of tunable laser outputs between 450 nm and 4500 nm for spectroscopy and imaging applications.
  1. Medical and Biomedical Applications:
  • RTP is used in laser systems for applications such as ophthalmology, dermatology, and surgical procedures.
  • Example: High-repetition-rate lasers for non-invasive medical diagnostics and treatment.
  1. High-Power Laser Systems:
  • RTP crystals are employed in high-power pulsed and continuous-wave (CW) lasers for industrial applications.
  • Example: Lasers for micromachining, welding, and 3D printing, where high damage thresholds and stability are essential.

RTP crystals provide unmatched performance in terms of stability, efficiency, and durability, making them suitable for a wide array of advanced optical and electro-optical systems.

Chemical and Structural Properties

Property

Specification

Crystal Structure

Orthorhombic

Lattice Parameters

a = 12.96 Å, b = 10.56 Å, c = 6.49 Å

Density

3.6 g/cm³

Melting Point

Approximately 1000 °C

Thermal Expansion Coefficients

a₁ = 1.01 × 10⁻⁵/°K, a₂ = 1.37 × 10⁻⁵/°K, a₃ = 4.17 × 10⁻⁶/°K

Sellmeier Equations (λ in μm)

nₓ² = 2.15859 + 0.09307/(λ² – 0.20994) – 0.01452λ²
nᵧ² = 2.23984 + 0.76303/(λ² – 0.23891) – 0.01585λ²
n𝓏² = 2.27722 + 1.11300/(λ² – 0.23454) – 0.01995λ²

Thermo-Optic Coefficient

dn/dT = 0.029 nm/°C

Electro-Optic Constants

γₓ = 38.5 pm/V (X-cut), γᵧ = 35 pm/V (Y-cut), γ𝓏 = 10.6 pm/V (Z-cut)

Electrical Resistivity

About 10¹⁰–10¹¹ ohm·cm

Optical and Nonlinear Optical Properties

Property

Specification

Transparency Range

350–4500 nm

SHG Phase Matching Range

Visible and infrared ranges

Damage Threshold

>1.8 GW/cm²

Refractive Indices

nₓ = 1.829, nᵧ = 1.850, n𝓏 = 1.899

Absorption Coefficients

<0.1% at 1064 nm, <1% at 532 nm

Nonlinear Coefficients

d₃₁ = 3.9, d₃₂ = 2.5, d₃₃ = 7.5 pm/V

Thermal-Optic Coefficients

dnₓ/dT = 1.1 × 10⁻⁵, dnᵧ/dT = 1.3 × 10⁻⁵, dn𝓏/dT = 1.6 × 10⁻⁵

Standard Fabrication Specifications

Property

Specification

Transparency Range

350–4500 nm

SHG Phase Matching Range

Visible and infrared ranges

Damage Threshold

>1.8 GW/cm²

Refractive Indices

nₓ = 1.829, nᵧ = 1.850, n𝓏 = 1.899

Absorption Coefficients

<0.1% at 1064 nm, <1% at 532 nm

Nonlinear Coefficients

d₃₁ = 3.9, d₃₂ = 2.5, d₃₃ = 7.5 pm/V

Thermal-Optic Coefficients

dnₓ/dT = 1.1 × 10⁻⁵, dnᵧ/dT = 1.3 × 10⁻⁵, dn𝓏/dT = 1.6 × 10⁻⁵

Spectrum Transmission Curve:

RTP transmission curves illustrate its excellent optical transparency over a wide wavelength range, minimizing absorption in UV, visible, and infrared regions.

Base Material

AR Coating

Reflectance

RTP

Dual Band AR (1064/532 nm)

R < 0.2% @ 1064 nm, R < 0.5% @ 532 nm

 

HR Coating (1064 nm)

R > 99.8% @ 1064 nm

 

Broad Band AR (350–4500 nm)

R < 2% over entire range

  • Adhesion Test Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.

 

Photonics On Crystals provides high-quality RTP crystals with advanced manufacturing capabilities, including:

  • Custom dimensions and coatings for specific applications.
  • High inventory availability for fast delivery.
  • Extensive technical support to ensure optimal performance in complex systems.

Standard Products

Dimensions (mm)

Length (mm)

Coatings

Application

Price (USD)

3 × 3

5

AR@1064/532 nm

SHG of Nd:YAG lasers

400

5 × 5

10

HR@1064 nm

High-power systems

550

7 × 7

15

BBAR (350–4500 nm)

OPO and spectroscopy

800

Custom

Custom

Upon Request

Custom Applications

TBD