POC-OC-122433-Yb:CaF2 Crystal

  • Isotropic crystal with cubic symmetry.
  • Long fluorescence lifetime and broad absorption bands.
  • Low quantum defect, suitable for high-power laser operations.
  • Wide optical transmission range (0.12 µm–10 µm).
  • Custom coatings available to meet specific requirements.

Customizable Components Available for This Material to Meet Your Specific Needs!

Yb:CaF2 Crystal Material General Description

Ytterbium-doped Calcium Fluoride (Yb:CaF2 Crystal) is a cutting-edge laser material offering a combination of low quantum defect and extended fluorescence lifetime. Synthesized using the Czochralski growth technique, Yb:CaF₂ is highly valued for its broad absorption bandwidth and minimal nonlinear effects under intense laser irradiation. These properties make it ideal for ultra-short pulse generation and high-power laser applications. Its cubic crystal structure ensures isotropy, which facilitates uniform optical behavior, and its low thermal expansion coefficient enhances thermal stability.

With a wide optical transmission range extending from 0.12 µm to 10 µm, Yb:CaF₂ is well-suited for femtosecond solid-state lasers. Additionally, the material’s low dispersion behavior minimizes phase distortion during laser pulse propagation. These unique properties enable its usage across scientific and industrial applications requiring precision and high energy efficiency.

 

Yb:CaF2 Crystal General Applications and Examples

Yb:CaF₂ crystals find applications in:

  • Femtosecond Laser Systems: Ideal for generating high-energy pulses with durations in the femtosecond range.
  • High-Power Laser Systems: Their high thermal conductivity and low quantum defect support high-power diode-pumped solid-state lasers.
  • Material Processing: Used in precise machining, micromachining, and laser welding.
  • Medical Lasers: Suitable for laser-based surgeries and dermatological procedures requiring high precision.
  • Scientific Research: Widely applied in research for ultra-fast phenomena and spectroscopy due to their broad absorption and emission spectra.

For example, Yb:CaF2 Crystal  is instrumental in diode-pumped systems generating femtosecond pulses at high average power for industrial and research applications.

Chemical and Structural Properties

Property

Value

Chemical Formula

Yb:CaF₂

Crystal Structure

Cubic

Cleavage Plane

(111)

Melting Point

1418 °C

Nonlinear Refractive Index

1.9 × 10^-16 cm²/W

Density

3.18 g/cm³

Thermal Conductivity

9.71 W/m·K

Thermal Expansion Coefficient

18.41 × 10^-6 K^-1

Mohs Hardness

4

Optical, Laser and Nonlinear Optical Properties

Property

Value

Absorption Peak Wavelength

979 nm

Absorption Cross Section @ 980 nm

5.4 × 10^-21 cm²

Emission Cross Section @ 1035 nm

2.3 × 10^-21 cm²

Fluorescence Lifetime

2.2 ms

Refractive Index @ 1035 nm

1.42866

Standard Fabrication Specifications

Parameter

Value

Orientation

(111)

Clear Aperture

> 90%

Surface Flatness

λ/10 @ 632.8 nm

Parallelism Error

< 20 arc sec

Perpendicularity Error

< 10 arc min

Chamfer

0.15 mm at 45°

Surface Quality (Scratch/Dig)

10/5

Dimensional Tolerance

Diameter: ±0.1 mm, Length: ±0.5 mm

Spectrum Transmission Curve:

The transmission curve reveals high optical transmission in the range of 0.12 µm to 10 µm, showcasing suitability for various wavelength operations.

POC-CaF2-2mm Crystal Spectrum Transmission Curves
POC-CaF2 Crystal Spectrum Transmission Curves

Coating Specification:

 

Coating Type

Reflection Coefficient

AR @ 980 nm–1060 nm

R < 0.2%

Custom Coatings

Available on request

  • Adhesion Test Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.

  • Temperature Test In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.

  • Abrasion Resistance Test Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.

  • Humidity Test Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.

  • Solvent and Cleaning Testing Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.

  • Salt Spray Test After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.

POC Strength and Capabilities

Photonics On Crystals (POC) excels in the production of high-precision laser crystals tailored to meet diverse industrial and research demands. With advanced manufacturing facilities and quality control protocols, POC ensures consistent performance and unmatched reliability. Customization options, from doping levels to coatings, further enhance compatibility with specialized laser systems.

Standard Products

Dimensions (mm)

Length (mm)

End Faces

Doping

Coatings

Price (USD)

10 × 10

10

Brewster-angle cut

1%

Uncoated

590

10 × 10

10

Right-angle cut

1%

AR @ 980 nm–1070 nm

590

3 × 3

5

Brewster-angle cut

3%

Uncoated

590

3 × 3

5

Right-angle cut

3%

AR @ 980 nm–1070 nm

590

Custom

Upon request

Upon request

Custom

Custom

Upon request