POC-OC-122469-KGW Crystal

  • Broad transparency range from 300 nm to 5 µm.
  • Two pump polarization-dependent Raman shifts at 768 cm⁻¹ and 901 cm⁻¹.
  • Excellent Raman shifter for picosecond applications.
  • Custom dimensions, orientation, and coatings available upon request.
  • High mechanical stability with superior thermal conductivity.

Customizable Components Available for This Material to Meet Your Specific Needs!

KGW Crystal  Material General Description

Potassium gadolinium tungstate (KGd(WO₄)₂, KGW) crystals are monoclinic crystals known for their excellent mechanical and optical properties. With a broad transparency range (0.3 µm to 5 µm) and significant thermal conductivity values, KGW are a reliable choice for demanding applications in Raman lasers and nonlinear optics. They offer two prominent Raman modes at 768 cm⁻¹ and 901 cm⁻¹, making them particularly effective for picosecond laser applications. KGW’s mechanical stability and ease of fabrication, combined with their strong polarization-dependent Raman effects, provide users with a versatile tool for advanced photonic applications.

KGW Crystal  General Applications and Examples

KGW  are extensively utilized in advanced photonic systems. Key application examples include:

  • Raman Laser Generators: KGW  serve as an active Raman medium in Raman laser systems, delivering high power with two distinct polarization-dependent Raman modes.
  • Nonlinear Optics: KGW’s excellent transparency and polarization properties make it a suitable candidate for second and third harmonic generation processes.
  • Picosecond Raman Shifters: The two prominent Raman shifts at 768 cm⁻¹ and 901 cm⁻¹ allow for frequency conversion in picosecond laser systems.
  • Laser Pumping: KGW are often employed in commercial Nd:YAG laser systems to achieve efficient Raman gain.
  • Scientific Research: KGW crystals are used in experimental setups requiring precise optical manipulation, especially in material science and physics.

These features make KGW an ideal crystal for Raman shifters, nonlinear optics, and other cutting-edge photonic applications.

Chemical and Structural Properties

Property

Value

Chemical Formula

KGd(WO₄)₂

Crystal Structure

Monoclinic, Space Group C2/c

Lattice Parameters

a = 10.6542(4) Å, b = 10.374(6) Å, c = 7.5820(2) Å

Density

7.27 g/cm³

Mohs Hardness

4-5

Transparency Range

0.3 µm – 5 µm

Thermal Conductivity (kₐ)

2.6 W·m⁻¹·K⁻¹

Thermal Conductivity (kᵦ)

3.8 W·m⁻¹·K⁻¹

Thermal Conductivity (k𝚌)

3.4 W·m⁻¹·K⁻¹

dn/dT (Temp Coefficient)

dn/dTₐ = -15.7 × 10⁻⁶ K⁻¹

 

dn/dTᵦ = -18.3 × 10⁻⁶ K⁻¹

 

dn/dT𝚌 = -17.3 × 10⁻⁶ K⁻¹

Optical, Laser and Nonlinear Optical Properties

Property

Value

Refractive Indices (nₐ)

nₐ = 1.982

 

nᵦ = 2.096

 

n𝚌 = 2.061

Raman Frequency Shifts

901 cm⁻¹, 768 cm⁻¹

Raman Linewidth

5.4 cm⁻¹ (polarization pump lp mlp)

 

6.4 cm⁻¹ (polarization pump gp lgp)

Raman Gain

11 cm/GW@532 nm

 

3 cm/GW@1064 nm

Dephasing Time

2 ps

Standard Fabrication Specifications

Specification

Value

Orientation

b-cut

Clear Aperture

>90%

Face Dimension Tolerance

±0.0/-0.1 mm

Length Tolerance

±0.1 mm

Parallelism Error

<20 arcsec

Perpendicularity Error

<10 arcmin

Surface Quality (Scratch/Dig)

10-5 S-D

Surface Flatness

<λ/8 @ 632.8 nm

Coatings

ARR@450-800 nm; 500-650 nm

Mount

Unmounted

Spectrum Transmission Curve:

KGW crystals exhibit high transmission in the range of 0.3 µm to 5 µm, allowing effective Raman shifting and nonlinear optical processes. The two Raman modes at 768 cm⁻¹ and 901 cm⁻¹ are distinctly visible in Raman scattering experiments, confirming the crystal’s excellent optical performance.

Coating Specification:

 

  • Anti-Reflection (AR) coatings available for 450-800 nm, 500-650 nm, or other custom wavelengths upon request.
  • High damage threshold coatings exceeding >10 J/cm² @ 1064 nm, 10 ns.
  • Adhesion Test Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.

POC Strength and Capabilities

 

Photonics On Crystals (POC) is a leading supplier of high-quality crystals designed for advanced photonic applications. Key strengths include:

  • Customizability: POC provides custom dimensions, orientations, and coating specifications tailored to customer needs.
  • Precision Fabrication: POC ensures rigorous quality control with tight tolerances and high damage threshold coatings.
  • Technical Expertise: POC offers comprehensive technical support for all products and applications.
  • Global Reach: With a global network, POC serves industries ranging from research to commercial laser systems.

Standard Products

Face Dimensions

Length

Coatings

Price (USD)

5 x 5 mm

15 mm

Uncoated

440

5 x 5 mm

30 mm

ARR@450-800 nm

600

5 x 5 mm

45 mm

Uncoated

610

5 x 5 mm

50 mm

ARR@450-800 nm

900

8 x 8 mm

50 mm

ARR@450-800 nm

1120