POC-OC-122495-Co2+:MgAl2O4 Crystal

  • High optical quality with uniform Co distribution.
  • High absorption cross-section enables passive Q-switching.
  • Negligible excited-state absorption for enhanced performance.
  • Wide transparency range for laser applications.
  • Exceptional durability with high damage threshold.

Customizable Components Available for This Material to Meet Your Specific Needs!

Cobalt-doped Magnesium Aluminate Spinel Crystal (Co2+:MgAl2O4 Crystal) Material General Description:

Co²⁺:MgAl₂O₄ Crystal, also known as Cobalt-doped Magnesium Aluminate Spinel Crystal, is a state-of-the-art passive Q-switch material. It is particularly effective in laser systems operating in the 1.2–1.6 µm spectral range, with peak performance in eye-safe lasers at 1.54 µm. The crystal features a cubic structure and substitutes cobalt ions for magnesium, offering a homogeneous doping profile. This results in uniform absorption properties that enhance laser performance without requiring additional corrective elements. Its high hardness and thermal stability make it suitable for high-power laser systems.

The negligible excited-state absorption of Cobalt-doped Magnesium Aluminate Spinel Crystal allows for a high contrast ratio in Q-switch operations. This crystal is particularly advantageous for erbium-doped lasers, facilitating compact and efficient passive Q-switching in both flash-lamp and diode-pumped systems. With high thermal conductivity and excellent mechanical strength, this crystal is ideal for demanding environments.

Co2+:MgAl2O4 Crystal   General Applications and Examples:

Co2+:MgAl2O4 Crystal  is widely used in:

  • Eye-Safe Lasers: Highly effective in passive Q-switching for erbium glass lasers at 1.54 µm. Commonly used in laser rangefinders, LIDAR systems, and remote sensing.
  • Medical Lasers: Provides compact, efficient laser systems for ophthalmic and dermatological treatments.
  • Industrial Applications: High durability makes it suitable for precision material processing lasers.
  • Defense and Aerospace: Used in compact laser designs for targeting and guidance systems.
  • Scientific Research: Ideal for laser spectroscopy due to its wide transparency and high absorption efficiency.

Example: Cobalt-doped Magnesium Aluminate Spinel  is commonly integrated into erbium glass laser systems for robust and high-contrast Q-switching with long operational lifetimes, even under high thermal loads.

Chemical and Structural Properties

Attribute

Value

Chemical Formula

Co²⁺:MgAl₂O₄

Crystal Structure

Cubic

Lattice Constant

8.07 Å

Density

3.62 g/cm³

Melting Point

2105 °C

Reflective Index

n = 1.6948 @ 1.54 µm

Stimulated Emission Cross-Section

0.033 W

Specific Heat Capacity

1.046 J/g·K

Thermal Expansion Coefficient

5.9 × 10⁻⁶ K⁻¹ @ 25 °C

Mohs Hardness

8.2

Extinction Ratio

25 dB

Lattice Orientation

[100] or [111] ± 0.5°

Optical Density

0.1–0.9

Damage Threshold

>500 MW/cm²

Co Doping Concentration

0.01–0.3 atm%

Optical, Laser and Nonlinear Optical Properties

Parameter

Value

Transparency Range

1.2–1.6 µm

Peak Performance Wavelength

1.54 µm

Absorption Cross-Section

3.5 × 10⁻¹⁹ cm²

Excited-State Absorption

Negligible

Thermal Conductivity

17 W/m·K

Laser Damage Threshold

>500 MW/cm²

Standard Fabrication Specifications

Specification

Value

Surface Flatness

λ/8 @ 632.8 nm

Parallelism

<10 arcmin

Perpendicularity Error

<0.1 mm at 45°

Surface Quality

10-5 S-D

Damage Threshold

>500 MW/cm²

Dimensions

Customizable

Spectrum Transmission Curve:

The spectrum curve for Co²⁺:MgAl₂O₄ shows high absorption cross-section around 1.54 µm, with minimal excited-state absorption across the transparency range (1.2–1.6 µm). This ensures a high Q-switch contrast ratio and efficient laser operation.

Coating Specification:

 

Coating Specification:

  • Anti-reflective coatings (AR) optimized for 1.2–1.6 µm wavelength range.
  • Custom coatings available upon request for specific laser systems.
  • Adhesion Test Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.

POC Strength and Capabilities

 

POC Strength and Capabilities: Photonics On Crystals (POC) excels in processing Co²⁺:MgAl₂O₄ crystals for diverse applications, offering:

  • Advanced crystal manufacturing techniques.
  • Customizable designs tailored to client specifications.
  • Expertise in high-damage-threshold crystal coatings.
  • Proven track record in laser system integration.

Standard Products

Face Dimensions

Initial Transmission

Coatings

Price (USD)

3 × 3 mm

85% @ 1.54 µm

AR @ 1.54 µm

400

5 × 5 mm

95% @ 1.54 µm

AR @ 1.54 µm

500

Customizable

As per request

As per request

On inquiry