POC-OC-122476-ZnS Crystal

  • Excellent optical transmission in the range of 0.37–14 µm.
  • High optical uniformity and stable chemical properties.
  • Low infrared absorption, ideal for infrared optics and thermal imaging systems.
  • Resistant to acid corrosion and suitable for high-performance optical applications.
  • Compatible with custom design coatings for enhanced optical performance.

Customizable Components Available for This Material to Meet Your Specific Needs!

Material General Description

Zinc Sulfide (ZnS) crystal is a wide-bandgap semiconductor material that exhibits superior optical transmission across the infrared spectrum (0.37–14 µm). Manufactured using Chemical Vapor Deposition (CVD), ZnS crystals are chemically stable, insoluble in water, and provide moderate density with ease of processing. Their low absorption and high optical uniformity make them the preferred choice for applications requiring advanced IR transparency, such as CO₂ laser optics, thermal imaging systems, and IR windows. The CVD ZnS is further processed with heat treatment to enhance its optical and mechanical properties, ensuring compatibility with high-precision optical systems.

General Applications

Zinc Sulfide crystals are widely utilized across numerous industries due to their excellent optical and mechanical properties. Some notable applications include:

  1. High-Power CO₂ Laser Systems: ZnS is commonly used for CO₂ laser optics, including lenses, beam splitters, and output windows, owing to its exceptional transmission in the IR range and resistance to thermal stress.
  2. Thermal Imaging and Infrared Sensors: ZnS serves as a core material for IR windows and thermal imaging systems, particularly in forward-looking infrared (FLIR) technology. Its broad transmittance range allows the detection of far-infrared wavelengths for high-resolution imaging.
  3. Military and Aerospace Applications: Due to its rugged optical performance, ZnS crystals are employed in laser guidance systems, infrared surveillance, and missile guidance technologies.
  4. Medical Science: ZnS optics are integrated into infrared diagnostic systems for non-invasive thermal imaging and medical sensors.
  5. Astronomy and Night Vision Systems: ZnS contributes to high-performance night vision equipment and infrared telescopes for astronomical observations.

Chemical and Structural Properties

Property

Value

Optical Transmission Range

0.37–14 µm

Refractive Index

2.35 @ 10.6 µm

Reflection Loss (both surfaces)

~10% @ 10.6 µm

Absorption Coefficient

<0.0005/cm @ 10.6 µm

Thermal Conductivity

27 W/mK

Laser Damage Threshold

>3 J/cm² @ 10 ns pulse (1064 nm)

Optical, Laser and Nonlinear Optical Properties

Property

Value

Optical Transmission Range

0.37–14 µm

Refractive Index

2.35 @ 10.6 µm

Reflection Loss (both surfaces)

~10% @ 10.6 µm

Absorption Coefficient

<0.0005/cm @ 10.6 µm

Thermal Conductivity

27 W/mK

Laser Damage Threshold

>3 J/cm² @ 10 ns pulse (1064 nm)

Standard Fabrication Specifications

Specification

Value

Clear Aperture

>90%

Surface Flatness

λ/8 @ 632.8 nm

Parallelism

<1 arcmin

Surface Quality

40–20 scratch-dig

Dimensional Tolerance

±0.1 mm

Chamfering

<0.25 × 45°

Coating Options

Available upon request

Spectrum Transmission Curve:

Two spectrum transmission curves demonstrate ZnS’s high transmission properties:

  • Curve 1: High transmission up to 75% from 400–1200 nm.
  • Curve 2: Near-perfect IR transmission in the range of 8000–12000 nm.

Coating Specification:

 

ZnS crystals can be provided with optional anti-reflective coatings to enhance performance for specific wavelengths. Coatings include:

  • Calcium Fluoride Coating: Available in 1–5 mm thickness.
  • Magnesium Fluoride Coating: Thickness ranges from 1–5 mm.
  • Custom coatings for extended IR or UV ranges are available upon request.
  • Adhesion Test Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.

POC Strength and Capabilities

 

Photonics On Crystals (POC) excels in delivering high-quality ZnS crystals tailored to various industries. With advanced manufacturing processes and rigorous quality control standards, POC ensures superior performance and reliability. POC provides custom coating solutions, precision engineering, and bulk manufacturing capabilities for a wide range of optical applications, offering optimal solutions for specialized needs in military, medical, and industrial sectors.

Standard Products

Dimensions (mm)

Coating

Price (USD)

10 × 10 × 2

Anti-Reflective (AR)

200

20 × 20 × 3

Broadband IR Coating

350

25 × 25 × 5

UV & IR Coating

400

50 × 50 × 5

Customizable

600

Custom Dimensions

Upon Request

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