POC-OC-122435-Cr4+:YAG Crystal

  • Exceptional thermal and chemical stability, resistant to UV degradation.
  • High damage threshold (>500 MW/cm² at 1064 nm, 10 ns, 10 Hz).
  • Wide transmission range (0.8 to 1.2 µm) suitable for Nd and Yb laser pumping.
  • Reliable passive Q-switch operation with tunable output.
  • Custom dimensions and initial transmission rates available for diverse applications.

Customizable Components Available for This Material to Meet Your Specific Needs!

General Description

Cr⁴⁺:YAG Crystal is an advanced material designed for passive Q-switching in solid-state lasers, such as Nd:YAG, Nd:YLF, and Nd:YVO₄. Its cubic garnet structure ensures durability, high thermal conductivity, and excellent damage threshold. Cr4+:YAG Crystal can efficiently operate without active electronic components, reducing system complexity and cost.

Photonics On Crystals provides Cr⁴⁺:YAG crystals with doping levels between 0.03 and 0.05 mol%. Available sizes range from 2 × 2 mm² to 14 × 14 mm² with lengths from 0.1 mm to 12 mm. Initial transmission can be tailored from 10% to 92% per customer requirements.

General Applications and Examples

Cr⁴⁺:YAG crystals are widely used for passive Q-switching, enabling compact laser designs for high-energy pulse generation. Examples include:

  • Laser Rangefinders: Efficient passive Q-switch operation for compact systems.
  • LIDAR Systems: Reliable short-pulse generation for high-resolution measurements.
  • Material Processing: Pulsed laser ablation for precision cutting and welding.
  • Medical Lasers: High-power pulse Cr4+:YAG Crystal  lasers for surgical and therapeutic applications.
  • Nonlinear Optics: Intracavity SHG (Second Harmonic Generation) to produce green outputs at 532 nm or UV outputs at 355 nm.

Chemical and Structural Properties

PropertySpecification
Chemical FormulaCr⁴⁺:Y₃Al₅O₁₂
Crystal StructureCubic Garnet
Dopant Concentration0.03–0.05 mol%
Mohs Hardness8.5
Refractive Index1.82 at 1064 nm
Damage Threshold>500 MW/cm² at 1064 nm
Melting Point1970°C

Optical, Laser and Nonlinear Optical Properties

PropertyValue
Transmission Range950–1200 nm
Refractive Index (1064 nm)1.82
Damage Threshold>500 MW/cm²
Ground-State Absorption (σₐ)4.4 × 10⁻¹⁹ cm² at 1064 nm
Emission Cross-Section (σₑ)8.2 × 10⁻²⁰ cm² at 1064 nm
Recovery Time (τ)3.4 µs

Standard Fabrication Specifications

SpecificationValue
Dimensions3 × 3 mm² to 20 × 20 mm²
Length0.1 mm to 12 mm
Dimensional Tolerance±0.05 mm
Surface Flatness< λ/10 @ 632 nm
Parallelism<20 arc seconds
Perpendicularity<15 arc minutes
Surface Quality (Scratch/Dig)20–10

Spectrum Transmission Curve

Cr⁴⁺:YAG exhibits a wide absorption band extending from 950 to 1200 nm with prominent peaks around 1020–1070 nm. The material is optimized for high-energy Nd and Yb laser pumping.

Coating Specification

AR Coating (1064 nm): Reflection <0.2%

Dual AR Coating: Reflection optimized for 1064 and 1070 nm

  • Adhesion Test: Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.

  • Temperature Test: In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.

  • Abrasion Resistance Test: Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.

  • Humidity Test: Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.

  • Solvent and Cleaning Testing: Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.

  • Salt Spray Test: After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.

Face DimensionsInitial TransmissionCoatingSKUPrice (USD)
6 × 6 mm²10%AR @1064 nm7201$220
6 × 6 mm²50%AR @1064 nm7202$230
6 × 6 mm²90%AR @1064 nm7203$240
3 × 3 mm²50%Dual AR Coating7210$210
Custom DimensionsCustomCustom CoatingCustomRequest Quote
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