POC-OC-122455-Yb:YLF Crystal

  • Broad and smooth emission spectrum with a wide tuning range.
  • High absorption cross-sections matching the wavelength of InGaAs laser diodes.
  • Low quantum defect for reduced thermal load.
  • Simple electronic structure excluding excited-state absorption.
  • Custom crystals and specifications available upon request.

Customizable Components Available for This Material to Meet Your Specific Needs!

General Description

Yb:YLF (Ytterbium-doped Lithium Yttrium Fluoride) crystals are advanced laser materials optimized for high-performance applications. Yb:YLF exhibits excellent thermal and mechanical properties, with a wide emission spectrum and broad absorption range centered around 960 nm, perfectly matching InGaAs laser diodes. Its low quantum defect ensures reduced thermal load during operation, making it an ideal choice for continuous-wave (CW) and mode-locked thin-disk laser applications. Yb:YLF’s simple electronic structure minimizes excited-state absorption and other detrimental quenching effects, offering high efficiency and reliability. This crystal’s low refractive index also eliminates the need for additional anti-reflective coatings in many applications.

General Applications and Examples

Yb:YLF crystals are widely used in:

  • Diode-Pumped Lasers: Ideal for mode-locked lasers requiring high repetition rates.
  • Thin-Disk Lasers: Suitable for femtosecond and picosecond pulse generation.
  • Medical Applications: Used in advanced surgical tools and laser therapy systems.
  • Material Processing: High-precision cutting, drilling, and marking.
  • Spectroscopy: Used in non-linear optical experiments and laser spectroscopy due to its broad emission spectrum.
  • Research and Development: Preferred in high-energy physics and laser research setups.

Example: Yb:YLF Crystal  has been extensively utilized in femtosecond laser systems, offering pulse durations of <100 fs, making it indispensable in ultrafast applications.

Chemical and Structural Properties

Property Value
Chemical Formula LiYF4:Yb
Dopant Yb 5-20 at.%
Density 3.95 g/cm³
Thermal Conductivity 6 W/mK
Mohs Hardness 5
Refractive Index n = 1.448
Melting Point 819°C
Emission Peak 1033 nm
Absorption Peak 960 nm
Thermal Expansion Coefficient 8-13 x 10^-6/K
Laser Wavelength 1017 nm
Lifetime of Yb³⁺ Energy Level 2.1 ms
Emission Cross-Section 4.1 x 10^-20 cm²

Optical Properties

Optical Property Value
Absorption Peak Wavelength 960 nm
Absorption Cross-Section 10.5 x 10^-20 cm²
Absorption Bandwidth at Peak 10 nm
Emission Peak Wavelength 1033 nm
Emission Cross-Section 4.1 x 10^-20 cm²
Lifetime of Yb³⁺ Energy Level 2.1 ms

Standard Fabrication Specifications

Parameter Specification
Orientation Z-cut, Brewster cut
Parallelism Error <20 arcsec
Perpendicularity Error <10 arcmin
Surface Quality 20-10 (Scratch/Dig)
Surface Flatness λ/10 @ 632.8 nm
Face Dimensions Tolerance ±0.1 mm
Protective Chamfers <0.1 mm at 45°
Laser-Induced Damage Threshold >10 J/cm² @ 1030 nm, 10 ns
Mount Unmounted

Spectrum Transmission Curve

The emission and absorption spectra are with absorption peaking at 960 nm and emission centered around 1033 nm, supporting a wide tuning range. This facilitates efficient diode-pumping and mode-locked operation.

POC-Yb YLF Crystal Spectrum Absorption and emission Curve

Coating Specification

  • Anti-Reflective (AR) Coating

    • Wavelength Range: 960 nm, 1030–1060 nm

    • Reflectance: <0.2%

  • Broadband AR Coating

    • Wavelength Range: 940–1060 nm

    • Reflectance: <0.2%

  • Adhesion Test: Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test: In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test: Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test: Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing: Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test: After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.
Face Dimensions Length End Faces Doping Coatings Price (USD)
3 x 3 mm 8 mm Right-Angle Cut 5% AR/AR @ 960-1060 nm 590
3 x 3 mm 8 mm Brewster-Angle Cut 5% Uncoated 540
e8 mm 8 mm Right-Angle Cut 5% AR/AR @ 960-1060 nm 680
3 x 3 mm 4 mm Brewster-Angle Cut 10% Uncoated 540
3 x 3 mm 2 mm Right-Angle Cut 10% AR/AR @ 960-1060 nm 590
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