POC-OC-122461-Tm:KYW Crystal

  • Broad fluorescence band for efficient lasing.
  • Large emission cross-section enabling high-energy output.
  • Relatively low upper-level lifetime for fast energy release.
  • Optically biaxial structure with excellent birefringence properties.
  • Custom crystal dimensions and specifications available upon request.

Customizable Components Available for This Material to Meet Your Specific Needs!

General Description

Tm:KYW (Thulium-doped Potassium Yttrium Tungstate) crystals are high-performance solid-state laser materials designed for CW and Q-switched laser applications emitting near the 2 µm wavelength range. The double tungstate structure of Tm:KYW  makes it optically biaxial, with a wide fluorescence band and large emission cross-section. These properties are especially valuable in generating femtosecond pulses in solid-state laser systems. Tm:KYW also demonstrates superior thermal stability, making it suitable for high-power operations while ensuring minimal thermal lensing effects.

General Applications and Examples

Tm:KYW crystals find application across a diverse range of fields due to their unique laser output capabilities and stable performance. Specific use cases include:

  1. Medical Applications: In surgery, particularly in laser ablation, implant procedures, and dermatology.
  2. Environmental Monitoring: Precision spectroscopy for atmospheric and pollutant analysis.
  3. Industrial Metrology: Integration into laser systems for material processing, distance measurement, and 3D mapping.
  4. Defense and Aerospace: Usage in laser rangefinders and lidar systems for advanced tracking and reconnaissance.
  5. Tm:KYW Crystal in Research: Generation of ultrafast femtosecond laser pulses in optical and photonics laboratories.

Chemical and Structural Properties

PropertyValue
Chemical FormulaTm:KY(WO₄)₂
Doping Concentration~5 at.% (typical)
Density6.5 g/cm³
Mohs Hardness4.5
Melting Point~1300°C
Crystal StructureMonoclinic
Refractive Index (1040 nm)2.015 (Np), 2.021 (Nm), 1.997 (Ng)
Thermal Conductivity3.5 W/m·K
Thermal Expansion Coefficientαx = 13 x 10⁻⁶, αy = 10 x 10⁻⁶, αz = 15 x 10⁻⁶ K⁻¹

Optical, Laser and Nonlinear Optical Properties

Optical PropertyValue
Absorption Peak Wavelength802 nm
Absorption Bandwidth~5.5 nm
Absorption Cross-Section5.2 × 10⁻²⁰ cm²
Emission Wavelength1910 nm
Emission Cross-Section1.15 × 10⁻²⁰ cm²
Fluorescence Lifetime17 µs
Typical Doping Level~5 at.%

Standard Fabrication Specifications

ParameterSpecification
OrientationNp-cut
Clear Aperture>90%
Face Dimensions Tolerance±0.1 mm
Length Tolerance±0.1 mm
Parallelism Error<20 arcsec
Perpendicularity Error<10 arcmin
Surface Quality20-10 S-D
Surface Flatnessλ/10 @ 632.8 nm
Protective Chamfers<0.1 mm × 45°
Laser Induced Damage Threshold (LIDT)>10 J/cm² @ 1900 nm, 10 ns
MountUnmounted

Spectrum Transmission Curve

Tm:KYW crystals exhibit broad absorption and emission bands peaking at 802 nm (absorption) and 1910 nm (emission). The wide spectral bandwidth supports their efficient lasing performance, especially for femtosecond pulse generation. The absorption curve demonstrates strong peaks in alignment with diode-pumping wavelengths, ensuring optimal energy transfer efficiency.

POC-Tm KYW Crystal Spectrum Absorption and emission Curve

Coating Specification

  • AR coating on both faces: R < 0.2% at 802 nm, 1900-2000 nm.
  • Custom coating configurations available upon request for specific laser systems.
  • Adhesion Test: Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test: In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test: Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test: Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing: Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test: After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.
Face DimensionsLengthEnd FacesDopingCoatingsPrice (USD)
3 x 3 mm2 mmBrewster-angle cut5%UncoatedRequest
3 x 3 mm2 mmRight-angle cut5%AR@802 nm + 1900-2000 nmRequest
CustomizableCustomCustomCustomCustom coating options availableRequest

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