POC-OC-122458-Er:Yb:Phosphate Glass

  • Long lifetime of the 4I11/2 erbium energy level.
  • High energy transfer efficiency between Yb to Er ions.
  • Wide absorption and emission cross-sections for improved performance.
  • Large bandwidth in absorption and emission, enabling versatile laser applications.
  • Custom crystals are available on request for specific laser designs.

Customizable Components Available for This Material to Meet Your Specific Needs!

General Description

Er,Yb:Phosphate Glass is a co-doped glass known for its excellent laser performance in the “eye-safe” spectral range of 1.5–1.6 µm. The material combines an extended erbium upper laser level lifetime (~8 ms) with a short lifetime (~2–3 ms) of the energy transfer stage between Yb and Er ions. This unique configuration allows efficient energy transfer, minimizing back-energy losses and improving overall system efficiency. Additionally, phosphate glass exhibits a low phonon energy, reducing non-radiative relaxations and enhancing luminescence quantum efficiency. Due to its superior optical and mechanical properties, Er,Yb:Phosphate Glass is widely used for creating compact, energy-efficient lasers operating in demanding applications.

General Applications and Examples

  • Range Finding: Ideal for passively Q-switched lasers used in rangefinder systems due to its “eye-safe” wavelength of 1.5–1.6 µm.
  • LIDAR: Reliable performance in light detection and ranging systems for industrial and environmental monitoring.
  • LIBS Systems: Suitable for Laser-Induced Breakdown Spectroscopy applications for material analysis.
  • Medical Applications: Can be implemented in laser treatments requiring precise and safe emission wavelengths.
  • Defense: Utilized in advanced targeting and distance measurement technologies due to its robust energy transfer efficiency and reliability in extreme conditions

Chemical and Structural Properties

PropertyUnitValue
Absorption Peak Wavelengthnm970
Absorption Cross-Sectioncm²1.7 × 10⁻²⁰
Absorption Bandwidthnm20
Laser Wavelengthnm1534
Emission Cross-Sectioncm²8 × 10⁻²⁰
Densityg/cm³2.93
Mohs Hardness6
Thermal ConductivityW/m·K0.65
dn/dT (Refractive Index Change)K⁻¹-2.1 × 10⁻⁶
Thermal Expansion CoefficientK⁻¹0.3–1.3 × 10⁻⁶
Typical Doping Levels0.1–1.0% (Er), 1.7–4% (Yb)

Optical, Laser and Nonlinear Optical Properties

PropertyValue
Refractive Index at 1534 nm1.52
Yb to Er Energy Transfer EfficiencyHigh
Emission Lifetime (4I11/2 level)~8 ms
Absorption Edge~970 nm

Standard Fabrication Specifications

PropertyValue
Clear Aperture>90%
Face Dimensions Tolerance±0.01 mm
Length Tolerance±0.1 mm
Parallelism Error<20 arcsec
Perpendicularity Error<10 arcmin
Surface Quality20–10 S/D
Surface Flatnessλ/10 @ 632.8 nm
MountUnmounted

Property

Value

Clear Aperture

>90%

Face Dimensions Tolerance

±0.01 mm

Length Tolerance

±0.1 mm

Parallelism Error

<20 arcsec

Perpendicularity Error

<10 arcmin

Surface Quality

20–10 S/D

Surface Flatness

λ/10 @ 632.8 nm

Mount

Unmounted

Spectrum Transmission Curve

A comprehensive transmission spectrum (graph shown) reveals the high absorption at ~970 nm and a strong emission at ~1534 nm, with minimal losses and consistent transmission efficiency over a broad wavelength range.

POC-Er Yb phosphate glass Crystal Spectrum Absorption and emission Curve

Coating Specification

Standard AR coatings available for dual wavelengths:

  • AR(R < 0.2%) @ 940 nm
  • AR(R < 0.2%) @ 1535 nm

Customized coatings available upon request.

  • Adhesion Test: Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test: In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test: Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test: Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing: Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test: After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.
Face DimensionsLengthEnd FacesDopingCoatingsPrice (USD)
3 × 3 mm5 mmBrewster-angle cutYb: 20%, Er: 1%Uncoated370
3 × 3 mm10 mmRight-angle cutYb: 20%, Er: 0.5%AR@940 nm + 1535 nm435
3 × 3 mm10 mmRight-angle cutYb: 20%, Er: 0.5%AR@940 nm + 1535 nm435
CustomizationAnyAnyAnyUpon requestUpon Request
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