POC-OC-122401- Infrared Germanium Window (N-Type)

  • Exceptional Infrared Transmission
    Germanium windows excel in transmitting infrared light across the 2–14 µm waveband, making them perfect for mid-wave and long-wave IR systems used in thermal imaging technologies.
  • High-Density and Durable Material
    With a density of 5.35 g/cc and semi-metallic properties, germanium ensures reliability and strength for demanding applications in aerospace, defense, and industrial sectors.
  • Thermal Sensitivity Management
    Germanium’s transmission efficiency decreases as temperatures rise, requiring careful thermal management in applications sensitive to heat.
  • Versatile Optical and Electronic Use
    As a semiconductor, germanium is vital in manufacturing transistors, integrated circuits, and optical coatings, supporting diverse electronic and optical technology applications.
  • Customizable Coating Options
    Germanium windows can be enhanced with coatings such as BBAR or DLC to optimize performance in the 8–12 µm range, tailored for specific industrial and scientific needs.

Customizable Components Available for This Material to Meet Your Specific Needs!

Germanium is a hard, brittle, semi-metallic substance with a greyish-white appearance and a specific density of 5.35 g/cc. As a metalloid on the periodic table, it embodies the best of both metal and non-metal characteristics, making it versatile for a wide range of applications. With a melting point of 937°C and vapor pressure of 10⁻⁴ Torr at 1,167°C, Germanium is robust and thermally stable. Its semiconductor nature mirrors silicon and plays a pivotal role in manufacturing transistors, integrated circuits, optical coatings, and optical storage media.

One distinctive feature of Germanium windows is their thermal escape characteristic. As temperatures increase, transmission efficiency decreases, requiring careful integration into thermal systems. Despite this, Germanium windows continue to lead the industry in performance, enabling innovations across critical sectors.

Germanium single crystal--used

General Specifications

POC offers Germanium windows tailored to meet precise customer demands. Below are the key specifications:

  • Material: Optical-Grade Monocrystalline Germanium (N-Type, resistivity of 5-40 ohm cm)
  • Transmission Range: Covers IR wavelengths from 3 to 14 microns
  • Refractive Index (10.6 µm): 4.0052
  • Absorbance at 10.6 µm: ≤ 0.035
  • Crystal Purity: Between 99.999% and 99.9999%
  • Surface Quality: 60/40 Scratch/Dig
  • Surface Flatness: ≤ 5 Fringes at 633 nm
  • Coating Options: Anti-Reflective (AR) or Diamond-Like Carbon (DLC) Coatings
    • AR coating (3-14 microns) or DLC in dark grey/black with transparency (Tavg) > 80%
    • Double-sided AR coating with transparency (Tavg) > 85%
  • Customization Options:
    • Diameter: 12 mm to 380 mm
    • Thickness Tolerance: ± 0.10 mm
    • Diameter Tolerance: +0.00/-0.05 mm
    • Edge Finish: Finely ground
    • Orientation: <111>
    • Surface Roughness: Ramax 0.2 µm to 4.0 µm

With its exceptional purity, precise dimensions, and superior coating options, POC’s Germanium windows are engineered to excel in demanding applications.

Physical Properties

Germanium’s physical properties support its broad applications across various industries. Below are key attributes

PropertyValue
Density (298K)5.35 g/cm³
Hardness800 kg/cm²
Young’s Modulus (298K)103.3 GPa (<100>)
Thermal Conductivity59.9 W/mK (300K)
Thermal Expansion Coefficient6.0 × 10⁻⁶ K⁻¹
Specific Heat Capacity322 J/kg K
Melting Point937°C
Resistivity0.03-50 Ω·cm
Purity> 99.999%

Optical Properties

Refractive Index by Wavelength:

Wavelength (µm)Refractive Index
24.10972
34.04550
44.02552
54.01652
64.01171
74.00878
84.00691
94.00557
104.00462
114.00388
124.00327
134.00278
144.00245

General Optical Characteristics:

PropertyValue
Transmission Spectrum (µm)2–14
Temperature Coefficient of Refractive Index (K)400 × 10⁻⁶
Refractive Index (10 µm)4.0052
Refractive Index Homogeneity≤ 5 × 10⁻⁴
Absorption Coefficient (10.6 µm, cm)≤ 0.0035
Optical Transmittance (10.6 µm)≥ 45.00%

General fabrication Specification

SpecificationValue
BevelProtective as needed
Coefficient of Thermal Expansion (CTE) (10⁻⁶/°C)6.1
EdgesFine Ground
Knoop Hardness (kg/mm²)780
Poisson’s Ratio0.28
Surface Flatness (P-V)λ/10 @ 10.6µm
Wavelength Range (nm)2000 – 14000
Clear Aperture (%)As Requested
Density (g/cm³)5.33
Index of Refraction (nᵈ)4.002 @ 11µm
Parallelism (arcmin)<3
SubstrateGermanium (Ge)
Surface Quality40-20
Young’s Modulus (GPa)102.7

POC offers Germanium (Ge) Windows with three options for anti-reflection coatings to cater to different infrared (IR) applications: a 3 – 5μm coating for mid-infrared use, a 3 – 12μm coating for broadband multispectral applications, and an 8 – 12μm coating for thermal imaging systems. Given germanium’s high index of refraction, approximately 4.0 across the 2 – 14μm wavelength range, applying an anti-reflection coating is crucial for achieving adequate transmission within the desired spectral region.

a 3mm thick Ge window with BBAR (3000-5000nm)

Typical transmission of a 3mm thick Ge window with BBAR (3000-5000nm) coating at 0° AOI. It indicates the coating design wavelength range, with the following specification: Ravg <3% @ 3000 – 5000nm

a 3mm thick Ge window with BBAR (3000-12000nm) coating at 0° AOI.

Typical transmission of a 3mm thick Ge window with BBAR (3000-12000nm) coating at 0° AOI. It indicates the coating design wavelength range, with the following specification:  Ravg <5.0% @ 3 – 12μm

POC offers Germanium (Ge) Windows with three options for anti-reflection coatings to cater to different infrared (IR) applications: a 3 – 5μm coating for mid-infrared use, a 3 – 12μm coating for broadband multispectral applications, and an 8 – 12μm coating for thermal imaging systems. Given germanium’s high index of refraction, approximately 4.0 across the 2 – 14μm wavelength range, applying an anti-reflection coating is crucial for achieving adequate transmission within the desired spectral region.

About DLC Coating:

            POC Diamond-Like Carbon (DLC) Coated Germanium Windows are crafted for robustness and longevity. These windows are equipped with a high-efficiency broadband anti-reflection coating on one side and a durable DLC coating on the opposite side, ensuring outstanding transmission and resistance to environmental conditions. The DLC-coated surface is engineered to endure extreme temperature fluctuations ranging from -80 to +160°F, continuous exposure to salt spray for 24 hours, salt solubility during a 24-hour immersion, and up to 5,000 wiper oscillations with a sand and slurry mixture. Moreover, POC DLC Coated Germanium Windows comply with the MIL-C-675C standards for severe abrasion resistance.

Germanium is prone to thermal runaway, a condition where its transmission efficiency declines as temperatures rise. Therefore, it is recommended to operate POC Germanium Windows at temperatures below 100°C to maintain optimal performance. Additionally, with a high density of 5.33 g/cm³, germanium windows should be carefully integrated into designs where weight sensitivity is a factor.

The material’s Knoop Hardness, at 780, is roughly double that of magnesium fluoride, making germanium windows exceptionally suitable for demanding IR applications where durable optics are essential.

POC offers Germanium (Ge) Windows with three options for anti-reflection coatings to cater to different infrared (IR) applications: a 3 – 5μm coating for mid-infrared use, a 3 – 12μm coating for broadband multispectral applications, and an 8 – 12μm coating for thermal imaging systems. Given germanium’s high index of refraction, approximately 4.0 across the 2 – 14μm wavelength range, applying an anti-reflection coating is crucial for achieving adequate transmission within the desired spectral region.

  • Adhesion Test Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.

Germanium Windows – Excellence in Infrared Transmission

At Photonics On Crystals (POC), we specialize in delivering world-class Germanium windows renowned for their superior transmission capabilities across the 2-14 µm waveband. These windows are integral to mid-wave and long-wave infrared (IR) systems, making them a popular choice for thermal imaging technologies. Whether in defense, aerospace, life sciences, medical applications, or industrial OEMs, Germanium windows offer exceptional performance and reliability, supporting cutting-edge advancements in infrared functionality.

Applications Across Industries

POC’s Optical Infrared Germanium windows serve diverse sectors with unparalleled efficiency:

  • Defense and Aerospace: Thermal imaging systems, night vision optics, and missile guidance.
  • Life and Medical Sciences: Biomedical imaging and infrared spectroscopy.
  • Industrial OEMs: Laser optics, infrared sensors, and environmental monitoring systems.
  • Semiconductor Industry: Integrated circuits, optical coatings, and storage media production.