Monocrystalline Germanium N Type Crystal AR Coated & DLC Coated, Ge Window

Germanium windows offer superior transmission capabilities in the 2-14 µm waveband, making them suitable for both mid-wave and long-wave infrared (IR) systems. As a prevalent choice in the production of IR windows and lenses, germanium is integral to thermal imaging technologies.

These high-density windows exhibit a thermal escape characteristic, where increased window temperatures lead to reduced transmission efficiency. Germanium windows are widely utilized across various sectors, including defense and aerospace industries, life and medical sciences, and industrial OEMs, among other applications requiring infrared functionality.

Customizable Components Available for This Material to Meet Your Specific Needs!

N-type germanium is a type of semiconductor that has been doped with elements to add extra electrons, making electrons the majority charge carriers. Below is a detailed overview of N-type germanium, including its properties, uses, and key characteristics.

Doping Elements:

  • Common Dopants: Phosphorus, arsenic, and antimony.
    • These elements have more valence electrons than germanium, contributing extra electrons to the semiconductor material.

Electrical Properties:

  • Majority Charge Carriers: Electrons.
  • Conductivity: Increased due to the abundance of free electrons.
  • Current Flow: Electrons move towards the positive terminal under an electric field, creating a flow of current.

Uses in Technology:

  • Semiconductor Devices:
    • Transistors: N-type germanium is used in the manufacture of bipolar junction transistors (BJTs) and field-effect transistors (FETs).
    • Integrated Circuits (ICs): Utilized in the production of various ICs due to its effective semiconductor properties.
  • Optical Applications:
    • Optical Storage Media: Germanium layers are vaporized under vacuum conditions to produce thin films used in CDs, DVDs, and Blu-ray discs.
    • Optical Coatings: Used in anti-reflective coatings and other optical components due to its favorable refractive index and optical properties.

Advantages:

  • Semiconductor Efficiency: Germanium has a higher electron mobility compared to silicon, which can improve the speed and efficiency of semiconductor devices.
  • Versatility: Functions well in both high-frequency and high-power applications, making it suitable for a wide range of electronic devices.

Comparison to Silicon:

  • Similarities:
    • Both germanium and silicon are group IV elements and act as semiconductors.
    • Used in similar applications, such as transistors and integrated circuits.
  • Differences:
    • Electron Mobility: Germanium has higher electron mobility than silicon, which can enhance device performance.
    • Thermal Properties: Germanium has a lower melting point compared to silicon (937°C vs. 1,414°C), which may influence the choice of material depending on the application.

Summary:

N-type germanium is a crucial material in the field of electronics and optics. With its unique combination of metalloid properties, high electron mobility, and effectiveness in semiconductor applications, it continues to be a valuable material in advanced technology manufacturing. Its use in transistors, integrated circuits, and optical coatings highlights its versatility and importance in modern electronics and optical devices.

General fabrication Specification

 

SpecificationValue
BevelProtective as needed
Coefficient of Thermal Expansion (CTE) (10⁻⁶/°C)6.1
EdgesFine Ground
Knoop Hardness (kg/mm²)780
Poisson’s Ratio0.28
Surface Flatness (P-V)λ/10 @ 10.6µm
Wavelength Range (nm)2000 – 14000
Clear Aperture (%)As Requested
Density (g/cm³)5.33
Index of Refraction (nᵈ)4.002 @ 11µm
Parallelism (arcmin)<3
SubstrateGermanium (Ge)
Surface Quality40-20
Young’s Modulus (GPa)102.7

POC offers Germanium (Ge) Windows with three options for anti-reflection coatings to cater to different infrared (IR) applications: a 3 – 5μm coating for mid-infrared use, a 3 – 12μm coating for broadband multispectral applications, and an 8 – 12μm coating for thermal imaging systems. Given germanium’s high index of refraction, approximately 4.0 across the 2 – 14μm wavelength range, applying an anti-reflection coating is crucial for achieving adequate transmission within the desired spectral region.

a 3mm thick Ge window with BBAR (3000-5000nm)

Typical transmission of a 3mm thick Ge window with BBAR (3000-5000nm) coating at 0° AOI. It indicates the coating design wavelength range, with the following specification: Ravg <3% @ 3000 – 5000nm

a 3mm thick Ge window with BBAR (3000-12000nm) coating at 0° AOI.

Typical transmission of a 3mm thick Ge window with BBAR (3000-12000nm) coating at 0° AOI. It indicates the coating design wavelength range, with the following specification:  Ravg <5.0% @ 3 – 12μm

POC offers Germanium (Ge) Windows with three options for anti-reflection coatings to cater to different infrared (IR) applications: a 3 – 5μm coating for mid-infrared use, a 3 – 12μm coating for broadband multispectral applications, and an 8 – 12μm coating for thermal imaging systems. Given germanium’s high index of refraction, approximately 4.0 across the 2 – 14μm wavelength range, applying an anti-reflection coating is crucial for achieving adequate transmission within the desired spectral region.

About DLC Coating:

            POC Diamond-Like Carbon (DLC) Coated Germanium Windows are crafted for robustness and longevity. These windows are equipped with a high-efficiency broadband anti-reflection coating on one side and a durable DLC coating on the opposite side, ensuring outstanding transmission and resistance to environmental conditions. The DLC-coated surface is engineered to endure extreme temperature fluctuations ranging from -80 to +160°F, continuous exposure to salt spray for 24 hours, salt solubility during a 24-hour immersion, and up to 5,000 wiper oscillations with a sand and slurry mixture. Moreover, POC DLC Coated Germanium Windows comply with the MIL-C-675C standards for severe abrasion resistance.

Germanium is prone to thermal runaway, a condition where its transmission efficiency declines as temperatures rise. Therefore, it is recommended to operate POC Germanium Windows at temperatures below 100°C to maintain optimal performance. Additionally, with a high density of 5.33 g/cm³, germanium windows should be carefully integrated into designs where weight sensitivity is a factor.

The material’s Knoop Hardness, at 780, is roughly double that of magnesium fluoride, making germanium windows exceptionally suitable for demanding IR applications where durable optics are essential.

POC offers Germanium (Ge) Windows with three options for anti-reflection coatings to cater to different infrared (IR) applications: a 3 – 5μm coating for mid-infrared use, a 3 – 12μm coating for broadband multispectral applications, and an 8 – 12μm coating for thermal imaging systems. Given germanium’s high index of refraction, approximately 4.0 across the 2 – 14μm wavelength range, applying an anti-reflection coating is crucial for achieving adequate transmission within the desired spectral region.

  • Adhesion Test Compliant with MIL-C-675C military standards, an adhesion test involved applying a tape that meets LT-90 specifications onto the lens film layer. The tape was affixed fully and then removed vertically. This procedure was performed three times, resulting in no blistering or peeling.
  • Temperature Test In line with MIL-C-675C specifications, test pieces were subjected to temperatures of -62±1℃ and 71±1℃. After maintaining them at room temperature (16℃~32℃) for two hours, the adhesion test was repeated, confirming no film detachment.
  • Abrasion Resistance Test Conforming to MIL-C-675C and CCC-C-440 standards, the abrasion resistance test involved a gauze tester applying a minimum force of 1.0 lbs (0.45 kg) to the film. This was repeated 25 times with gauze widths of 1/4 inch (6.4mm) and 3/8 inch (9.5mm), ensuring no damage occurred to the film surface.
  • Humidity Test Under MIL-C-675C criteria, the test piece was placed in a controlled temperature and humidity chamber set to 49 ±2℃ and 95%~100% humidity for 24 hours. The film remained intact, with no peeling, scratches, or other defects.
  • Solvent and Cleaning Testing Following MIL-C-675C specifications, test pieces were exposed to room temperature conditions (16℃~32℃) and tested with acetone and alcohol for at least 10 minutes each. After air drying and subsequent cleaning with a cotton cloth soaked in alcohol, the film surface showed no signs of peeling or scratches.
  • Salt Spray Test After 100 hours in a 35°C environment with a 5% saltwater concentration, the film showed no signs of damage.

 

Germanium Windows – Excellence in Infrared Transmission

At Photonics On Crystals (POC), we specialize in delivering world-class Germanium windows renowned for their superior transmission capabilities across the 2-14 µm waveband. These windows are integral to mid-wave and long-wave infrared (IR) systems, making them a popular choice for thermal imaging technologies. Whether in defense, aerospace, life sciences, medical applications, or industrial OEMs, Germanium windows offer exceptional performance and reliability, supporting cutting-edge advancements in infrared functionality.

Applications Across Industries

POC’s Optical Infrared Germanium windows serve diverse sectors with unparalleled efficiency:

  • Defense and Aerospace: Thermal imaging systems, night vision optics, and missile guidance.
  • Life and Medical Sciences: Biomedical imaging and infrared spectroscopy.
  • Industrial OEMs: Laser optics, infrared sensors, and environmental monitoring systems.
  • Semiconductor Industry: Integrated circuits, optical coatings, and storage media production.